Journal
ORGANIC LETTERS
Volume 12, Issue 17, Pages 3886-3889Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101588j
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Funding
- Deutsche Forschungsgemeinschaft [SFB 623]
- Fonds der Chemischen Industrie
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A modular synthesis of cyclohexenones is described and applied to the first enantioselective total syntheses of (+)-crypto- and (+)-infectocaryone. Key steps in the synthesis of cyclohexenones are an iridium-catalyzed allylic alkylation, nucleophilic allylation, and ring-closing metathesis. On the way to (+)-cryptocaryone, a catch and release strategy involving an iodolactonization/elimination and a regioselective C-acylation were used.
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