Journal
ORGANIC LETTERS
Volume 12, Issue 7, Pages 1400-1403Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100172w
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- TUBA (Turkish Academy of Sciences)
- TUBITAK
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Two Bodipy derivatives with silyl-protected phenolic functionalities signal fluoride concentrations both in solution and in a poly(methyl methacrylate) matrix. The exact location of the nascent phenolate group Is Important. If it is at the meso position, photoinduced electron transfer is triggered; however, if it is in full conjugation via a styryl moiety to the Bodipy core, strong Intramolecular charge transfer is triggered, resulting in a large red shift in the absorbance peak. In either case, a selective methodology for fluoride sensing is the invariable result.
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