Journal
ORGANIC LETTERS
Volume 12, Issue 10, Pages 2246-2249Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1005938
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Funding
- PRF [48764-GB4]
- Kentucky EPSCoR [REG 2008]
- NIH [GM48722]
- NSF [CHE-0601857]
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The title complexes catalyze the aerobic oxidations of hydrocarbons using visible light and atmospheric oxygen as oxygen source in sequences employing photodisproportionation reactions. The putative oxidants, ruthenium(V)-oxo porphyrin species, can be detected and studied in real time via laser flash photolysis methods.
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