Journal
ORGANIC LETTERS
Volume 12, Issue 23, Pages 5378-5381Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102029u
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Funding
- NSF [0718275]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0718275] Funding Source: National Science Foundation
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Lithium diisopropylamide (LDA) promotes virtually quantitative conversion of allylic ethers to (Z)-propenyl ethers. It was discovered that allylic ethers can be isomerized efficiently with very high stereoselectivity to (Z)-propenyl ethers by LDA in THF at room temperature. The reaction time for the conversion increases with more sterically hindered allylic ethers. Different amides were also compared with LDA for their ability to effect this isomerization.
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