Journal
ORGANIC LETTERS
Volume 12, Issue 10, Pages 2310-2313Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100667z
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- Department of Chemistry and Biochemistry
- College of Arts and Sciences
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Cucurbit[6]-, [7]-, and [8]uril can catalyze the silver(I)-promoted desilylation of trimethylsilylalkynyl-containing pseudorotaxanes by stabilizing a key pi-alkynyl silver intermediate through favorable interactions between the metallic cation and the cavitand carbonylated portal.
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