Journal
ORGANIC LETTERS
Volume 12, Issue 24, Pages 5616-5619Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102254q
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Funding
- European Commision [FP7-201431]
- PolyU Internal Grant DA (A-PDOX)
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An effective organocatalytic asymmetric aldol reaction of acetone to beta,gamma-unsaturated alpha-keto ester has been developed. In the presence of 5 mol % of 9-amino (9-deoxy)-epicinchona alkaloid and 10 mol A of 4-nitrobenzoic acid, the aldol adducts containing a chiral tertiary alcohol moiety were obtained in excellent yields and enantioselectivities.
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