4.8 Article

Proton Affinities of Phosphines versus N-Heterocyclic Carbenes

Journal

ORGANIC LETTERS
Volume 12, Issue 21, Pages 4764-4767

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol101864p

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Funding

  1. NSF
  2. Alfred P. Sloan Foundation
  3. National Center for Supercomputer Applications
  4. Division Of Chemistry
  5. Direct For Mathematical & Physical Scien [0953464] Funding Source: National Science Foundation

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The gas-phase proton affinities of unusually basic phosphines and N-heterocyclic carbenes are compared and contrasted both computationally and experimentally.

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