4.8 Article

Intermolecular Aerobic Oxidative Allylic Amination of Simple Alkenes with Diarylamines Catalyzed by the Pd(OCOCF3)2/NPMoV/O2 System

Journal

ORGANIC LETTERS
Volume 12, Issue 6, Pages 1372-1374

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol100292g

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan
  2. Kansai University Research Grants

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Intermolecular aerobic oxidative allylic amination of simple alkyl alkenes with simple amines such as diphenylamine was induced by a Pd(OCOCF3)(2)/NPMoV catalytic system, leading to the corresponding (E)-allylamines In good yield and selectivity through the formation of (eta(3)-allyl)palladium(II) trifluoroacetate species as a possible key intermediate.

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