4.8 Article

Iron-Catalyzed Redox Radical Cyclizations of 1,6-Dienes and Enynes

Journal

ORGANIC LETTERS
Volume 12, Issue 1, Pages 112-115

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol902562j

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan

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Treatment of 1,6-dienes and enynes with FeCl3 or Fe(Pc) in the presence of NaBH4 and air or O-2 causes radical cyclization to give five-membered carbo or heterocyclic compounds, Into which a halogen atom or hydroxyl group was introduced.

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