Journal
ORGANIC LETTERS
Volume 12, Issue 8, Pages 1672-1675Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100109j
Keywords
-
Categories
Funding
- Centre National de la Recherche Scientifique
- Ministere de la Recherche et des Nouvelles Technologies
Ask authors/readers for more resources
A boradiazaindacene (BODIPY) fluorophore with a chirality held on the central boron has been synthesized and the racemate resolved. Dissymetrization of the BODIPY core was obtained by oxidation of the 3-methyl group to the corresponding carboxaldehyde. A hydrogen bond between the aldehyde proton and the fluorine on the boron atom was evidenced by both H-1 NMR and X-ray diffraction. Chiral high-performance liquid chromatography as well as circular dichroism confirm the persistence of both enantiomers.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available