Journal
ORGANIC LETTERS
Volume 12, Issue 6, Pages 1184-1187Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902923e
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- NIH [GM-080422]
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A 1:1 mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgSbF6 catalyzes the Intermolecular amination of allylic alcohols with 1-methylimidazolidin-2-one and related nucleophiles that, in the case of gamma-unsubstituted or gamma-methyl-substituted allylic alcohols, occurs with high gamma-regloselectivity and syn-stereoselectivity.
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