Journal
ORGANIC LETTERS
Volume 12, Issue 1, Pages 40-42Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9024309
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A simple and efficient method for constructing 1,4-oxazepines and 1,3-oxazines was developed with use of a phosphine-mediated tandem reaction of ynones with 2-azido alcohols. The method offers a promising route to synthetically useful as well as biologically active heterocycles under mild conditions and may be exploited for the preparation of interesting chiral ligands.
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