Journal
ORGANIC LETTERS
Volume 12, Issue 12, Pages 2706-2709Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1007444
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Funding
- National Institutes of Health [GM038436, GM026782]
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delta-Methyl-substituted homoallylic alcohols 2 were prepared in 71-88% yield, E:Z>30:1 and 93% to >95% ee via BF3 center dot Et2O-promoted allylboration with alpha-Me-allylboronate 1. The origin of high (E)-selectivity is proposed.
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