Journal
ORGANIC LETTERS
Volume 12, Issue 21, Pages 4944-4947Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102081q
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- National Science Foundation [CHE-0719437]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [840336] Funding Source: National Science Foundation
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The convergent synthesis of geometrically degradable dendrimers based on the 2,4-bis(hydroxymethyl)phenol subunit is presented. The key step of the synthetic scheme involves the CuI/3,4,7,8-tetramethyl-1,10-phenanthroline-catalyzed coupling of aryl iodides and alcohols. The synthesis and disassembly of these compounds is discussed.
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