Journal
ORGANIC LETTERS
Volume 12, Issue 15, Pages 3484-3487Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101318t
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- Ministerio de Educacion y Ciencia [CTQ2007-61462]
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A novel one-pot tandem asymmetric Hantzsch-type process has been employed to generate fluorinated 1,4-dihydropyridines (1,4-DHPs) as single diastereoisomers. It involves the condensation of (R)-(+)-allyl p-tolyl sulfoxide, fluorinated nitriles, and alkyl propiolates, giving access to a new family of enantiomerically pure fluorine-containing 1,4-DHPs.
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