N-Annulated Perylene Fused Porphyrins with Enhanced Near-IR Absorption and Emission

N-Annulated perylene fused porphyrins 1 and 2 were synthesized by oxidative dehydrogenation using a Sc(OTf)(3)/DDQ system. These newly synthesized hybrid molecules are highly soluble in organic solvents and exhibit remarkably intense near-IR absorption, as well as detectable photoluminescence quantum yields, all of which are comparable to or even exceed those of either meso-beta doubly linked porphyrin dimer/trimer or bis/tri-N-annulated rylenes.