Journal
ORGANIC LETTERS
Volume 12, Issue 20, Pages 4655-4657Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101894h
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Funding
- National Natural Science Foundation of China [29825104, 29632003, 20632070]
- Application of Nuclear Techniques in Agriculature [200803034]
- National Basic Research Program of China [2010CB126103]
- SIOC startup funds
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An efficient, highly enantioselective, organocatalytic Michael addition reaction of aldehydes with trilluoroethylidene malonates is described The asymmetric reaction provided highly optically pure beta-trifluoromethyl aldehydes which can be conveniently transformed into 4,4,4-trifluoromethyl butyric acid and trifluoromethyl substituted delta-lactones without loss in enantioselectivity
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