Journal
ORGANIC LETTERS
Volume 12, Issue 20, Pages 4560-4563Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1018536
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Funding
- UC Berkeley
- NSF [0643264]
- EhLilly
- Glaxo-SmithKline
- Johnson and Johnson
- Amgen
- AstraZencca
- Direct For Mathematical & Physical Scien [0643264] Funding Source: National Science Foundation
- Division Of Chemistry [0643264] Funding Source: National Science Foundation
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The tetracyclic framework of the tetrapetalone A aglycon has been secured through synthesis A reductive pyrrole alkylation enables the formation of a key tetrasubstituted carbon stereocenter, and the tetramic acid portion of the molecule can be accessed through silicon or boronic ester conjugate addition to an ene-lactam
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