4.8 Article

Bis-exo-2-norbornylboron Triflate for Stereospecific Enolization of 3,3,3-Trifluoropropionates

Journal

ORGANIC LETTERS
Volume 12, Issue 20, Pages 4474-4477

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol1016178

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Funding

  1. Herbert C Brown Center for Borane Research

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The first boron-mediated enolization-aldolization of 3.3,3-Influoropropionates has been reported The preparation and application of bis-exobicyclo[221]heptan-2-ylboron Inflate as a superior reagent for diastereospecific enolization has also been described.

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