4.8 Article

Regioselective Carboindation of Simple Alkenes with Indium Tribromide and Ketene Silyl Acetals

Journal

ORGANIC LETTERS
Volume 12, Issue 15, Pages 3390-3393

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol1012108

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [18065015, 20036036, 19550038]
  2. Grants-in-Aid for Scientific Research [19550038, 18065015, 20036036] Funding Source: KAKEN

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The regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals was accomplished. Various alkenes such as ethylene, 1-alkenes, and cyclic alkenes were applicable for this reaction system. The alkylindium product from the carboindation of cyclohexene revealed an anti addition mechanism.

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