Journal
ORGANIC LETTERS
Volume 12, Issue 15, Pages 3494-3497Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101329d
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Funding
- MEXT, Japan [19027005, 20036005]
- JSPS [19390001]
- Research Foundation for Pharmaceutical Sciences
- Grants-in-Aid for Scientific Research [19027005, 19390001, 20036005] Funding Source: KAKEN
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A nickel-catalyzed intramolecular cyclization of alkynylalkanone in the presence of Et(3)SiH using an NHC ligand produced various carbo- and heterocycles In a stereoselective manner. The reaction would proceed via formation of oxanickelacycle followed by sigma-bond metathesis with silane to give a bi- or tricyclic compound.
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