4.8 Article

Synthesis of α,α′-Linked Oligophospholes and Polyphospholes by Using Pd-Cul-Promoted Stille-Type Coupling

Journal

ORGANIC LETTERS
Volume 12, Issue 11, Pages 2675-2677

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol100926q

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [21108511, 22350016]
  2. Grants-in-Aid for Scientific Research [21108511, 22350016] Funding Source: KAKEN

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Palladium-copper-promoted Stille-type cross-coupling reactions between alpha-stannylphospholes and alpha-iodophospholes afforded alpha,alpha'-linked oligophospholes and polyphosphole efficiently. It has been revealed that the polyphosphole P-oxide possesses an extremely narrow band gap and a high electron-accepting ability as compared to polythiophene.

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