Journal
ORGANIC LETTERS
Volume 12, Issue 8, Pages 1660-1663Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100093u
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- Deutsche Forschungsgemeinschaft
- Bayer-Schering
- Pharma AG
- Bayer Services GmbH
- BASF AG
- Sasol GmbH
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A highly, stereo- and regioselective Meerwein - Ponndorf - Verley - Aldol etherification process of enolizable aldehydes is described. This new transformation is catalyzed by trifluoroacetic acid. The method also allows cross-aldol reactions with alpha-branched enolizable aldehydes and thus provides access to defined configured quaternary stereogenic centers.
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