4.8 Article

Asymmetric Synthesis and Photophysical Properties of Benzopyrano- or Naphthopyrano-Fused Helical Phosphafluorenes

Journal

ORGANIC LETTERS
Volume 12, Issue 6, Pages 1324-1327

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol100227k

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Funding

  1. MEXT, Japan [20675002]
  2. Grants-in-Aid for Scientific Research [20675002] Funding Source: KAKEN

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Enantioenriched benzopyrano- and naphthopyrano-fused helical phosphafluorenes have been synthesized by the rhodium-catalyzed enantioselective double [2 + 2 + 2] cycloaddition of dialkynyl phosphorus compounds with phenol- or naphthol-linked tetraynes. Photophysical properties of these phosphafluorenes are also disclosed.

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