Journal
ORGANIC LETTERS
Volume 12, Issue 2, Pages 276-279Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902602c
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An enantioselective hydrogenation of hydrazones catalyzed by Rh complexes (Rh-Josiphos or Rh-Taniaphos) has been developed. The protocol can be applied to hydrazones with three different protective groups (Boc, Cbz, and methoxycarbonyl), allowing for selective deprotection and further elaboration of the hydrazine products in the presence of other functional groups.
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