Journal
ORGANIC LETTERS
Volume 12, Issue 2, Pages 380-383Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902723q
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Funding
- Natural Sciences and Engineering Research Council of Canada
- Ministere de I'Education dU Quebec
- Canada Foundation for Innovation
- Canada Research Chairs Program
- Universite de Montreal
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Acetylene sponges can be created by taking advantage of the nonplanar geometry of hexaphenylbenzenes and the special capacity of the central aromatic ring to engage in C(sp)-H center dot center dot center dot pi interactions reinforced by secondary C(sp(2))-H center dot center dot center dot pi interactions, as revealed by X-ray crystallographic studies and DFT calculations.
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