Syntheses and Crystal Structures of Benzohexathia[7]helicene and Naphthalene Cored Double Helicene

Bis(trimethylsilyl)benzohexathia[7]helicene 1, naphthalene cored double helicene 2 (the fused dimer of 1), and a novel ten-membered cyclic diketone with four moieties of dithieno[2,3-b:3',2'-d]thiophene (3) were efficiently synthesized. Their crystal structures were determined with single-crystal X-ray analysis, In their crystal packings, they all show mutiple short contacts including intermolecular pi...pi, pi...S, and S...S interactions. UV/vis spectra indicate that significant T-electron delocalization existed in 1, 2, and 3.