Journal
ORGANIC LETTERS
Volume 12, Issue 12, Pages 2778-2781Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100877g
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Funding
- ETH [TH-05 07-1]
- Swiss National Fund [200021-129660]
- Swiss National Science Foundation (SNF) [200021_129660] Funding Source: Swiss National Science Foundation (SNF)
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New macrocyclic amphiphiles with two or three integrated 1,8-anthrylenes have been synthesized by an iterative Sonogashira cross-coupling protocol. The final cyclization has been conducted with 80% yield under cuprous-free dilution conditions. Formation of a monolayer at the air/water interface has also been demonstrated. These results open the intriguing possibility to construct large 2D supramolecular/macromolecular systems for which unique photophysical and -chemical properties are expected.
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