Journal
ORGANIC LETTERS
Volume 12, Issue 1, Pages 100-103Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902489a
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Funding
- National Natural Science Foundation of China [20572025, 20872037]
- Laboratory of Organic Functional Molecules
- Sino-French Institute of ECNU
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An efficient iron-catalyzed, microwave-promoted cascade benzylation-cyclization of phenols Is reported. Benzyl acetates, benzyl bromides, and benzyl carbonates are suitable benzylating reagents. The reactions proceed to afford both 9-aryl and 9-alkyl xanthene derivatives In good to high yields using FeCl3 as the catalyst under MW irradiation conditions.
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