Journal
ORGANIC LETTERS
Volume 12, Issue 23, Pages 5546-5549Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102521q
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Funding
- Major State Basic Research Development Program [2010CB833302]
- Chinese Academy of Sciences [KJCX2-YW-11-07]
- Shanghai Municipal Committee of Science and Technology [09JC1417300]
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The first palladium-diene-catalyzed asymmetric Suzuki-Miyaura coupling reaction has been achieved. A number of functionalized biaryls were obtained in high yields and in moderate to high enantioselectivities. The existence of an ortho-formyl group greatly improves the catalyst efficiency and permits further synthetic elaborations.
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