Journal
ORGANIC LETTERS
Volume 12, Issue 19, Pages 4396-4399Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101889h
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- MRES
- CNRS
- IUF
- ANR [0302]
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The gold(I)-catalyzed cycloisomerization of beta-allenylhydrazones provides an efficient access to multisubstituted N-aminopyrroles, which are obtained in good to excellent yields. This new intramolecular cyclization method can be applied either to alkyl- or aryl-substituted allenes. The reaction proceeds under mild conditions with short reaction times through a selective intramolecular 1,2-alkyl or -aryl migration extending the general scope of the reaction.
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