4.8 Article

Annulation of Tetrathiafulvalene to the Bay Region of Perylenediimide

Journal

ORGANIC LETTERS
Volume 12, Issue 6, Pages 1344-1347

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol1002708

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Funding

  1. Swiss National Science Foundation [200020-116003]

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A tetrathiafulvalene donor has been annulated to the bay region of perylenedilmide affording a new pi-conjugated molecular dyad. Various electronic excited charge-transfer states are generated in different oxidation states, leading to almost full absorption in the visible to near-IR region with a high extinction coefficient.

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