Journal
ORGANIC LETTERS
Volume 12, Issue 23, Pages 5518-5521Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1024037
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Funding
- National Research Foundation of Korea [2009-0073839]
- National Research Foundation of Korea [2009-0073839] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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2,2-Difluoro-1-tributylstannylethenyl p-toluenesulfonate (2) was reacted with aryl iodides in the presence of 10 mol % of Pd(PPh3)(4) and 10 mol % of Cul in DMF at 80 degrees C for 10-20 h to give the cross-coupled products 3 in 35-97% yields. Further coupling reaction of 3 with arylstannanes in the presence of 5 mol % of Pd(PFh(3))(4) and 3 equiv of LiBr in DMF at 100 degrees C for 2-24 h afforded the desired products 5 in 25-78% yields.
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