Journal
ORGANIC LETTERS
Volume 12, Issue 19, Pages 4376-4379Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101859p
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Funding
- National Science Foundation of China [20772145]
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A new strategy for the synthesis of poly-substituted 3-H, 3-F, and 3-trifluoromethyl pyridines based on C-F bond breaking of the anionically activated fluoroalkyl group is described. A series of 2,6-disubstituted 4-amino pyridines were prepared through this domino process in high yields under noble metal-free conditions, making this method a supplement to pyridine synthesis.
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