Journal
ORGANIC LETTERS
Volume 12, Issue 19, Pages 4428-4430Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101907k
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Funding
- National Science Foundation [CHE-0714828, CHE-0234811, CHE-0840509]
- Welch Foundation [Y-1407]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0840509] Funding Source: National Science Foundation
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A unique one-pot, high-yield desulfurative fluorination bromination reaction which leads to the synthesis of 2,5-dibromo-3-(1,1-difluoroalkyl)thiophenes is reported. A single dithiolane reactant can be used to produce both 2,5-dibromo-3-(1,1-difluoroalkyl)thiophene and 3-(1,1-difluoroalkyl)thiophene with longer alkyl chains.
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