Journal
ORGANIC LETTERS
Volume 12, Issue 13, Pages 2904-2907Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1006604
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Funding
- National Institute of General Medical Sciences [NIH P050-GM069663, NIH-STTR R41 GM076765]
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The development of new ROMP-based oligomeric benzyl phosphates (OBPn) is reported for use as soluble, stable benzylating reagents. These oligomeric reagents are readily synthesized from commercially available materials and conveniently polymerized and purified in a one-pot process, affording bench-stable, pure white, free-flowing solids on multigram scale. Utilization in benzylation reactions with a variety of nucleophiles is reported.
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