Journal
ORGANIC LETTERS
Volume 12, Issue 22, Pages 5346-5349Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102407k
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Funding
- Program for Promotion of Basic and Applied Research for Innovations in Bio-oriented Industry (BRAIN)
- JSPS
- [19390007]
- [22390002]
- Grants-in-Aid for Scientific Research [22390002] Funding Source: KAKEN
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The first catalytic acylation of alcohols with a thiol ester present in Wittig reagents under neutral conditions catalyzed by the Cu(II) salt through a push pull mechanism is reported. Furthermore, a new methodology for the one-pot lactonization of acyloins by a copper catalyst is developed. The synthetic utility of this method for the synthesis of natural products is shown.
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