Journal
ORGANIC LETTERS
Volume 12, Issue 7, Pages 1496-1499Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100211s
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Funding
- French ministry of research
- Central Glass Co.
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Using a trifluoromethylated oxazolidine (Fox) chiral auxiliary, the hydroxylation reaction of enolates was very efficiently performed under smooth and friendly conditions with molecular oxygen as oxidizer. This reaction occurred with an extremely high diastereoselectivity. After cleavage, the chiral auxiliary is efficiently recovered and highly valuable enantiopure oxygenated carboxylic acids and alcohols are released.
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