Journal
ORGANIC LETTERS
Volume 12, Issue 11, Pages 2514-2516Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1007235
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- Robert A. Welch Foundation
- NIH-NIGMS [RO1-GM069445]
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Exposure of alcohols to allenamides in the presence of RuHCl(CO)(PPh(3))(3) and dippf [dippf = bis(diisopropylphosphino)ferrocene] results in hydrogen transfer to generate aldehyde-allylruthenium pairs, which engage in C-C coupling to form products of carbonyl aminoallylation as single anti-diastereomers.
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