Journal
ORGANIC LETTERS
Volume 11, Issue 12, Pages 2687-2690Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900799e
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- Ministry of Education, Culture, Sports, Science and Technology, Japan [1320350021]
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An enantioselective total synthesis of (-)-agelastatin A from (-)-2,3-O-isopropylidene-D-threitol is described. The sequential Overman/ Mislow-Evans rearrangement of the allylic bistrichloroimidate is the key step, which efficiently installed a diaminohydroxy group.
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