4.8 Article

IBS-Catalyzed Oxidative Rearrangement of Tertiary Allylic Alcohols to Enones with Oxone

Journal

ORGANIC LETTERS
Volume 11, Issue 15, Pages 3470-3473

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol9013188

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Funding

  1. JSPS.KAKENHI [20245022]
  2. New Energy and Industrial Technology Development Organization (NEDO)
  3. MEXT
  4. Grants-in-Aid for Scientific Research [20245022] Funding Source: KAKEN

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A 2-iodoxybenzenesulfonic acid (IBS)-catalyzed oxidative rearrangement of tertiary allylic alcohols to enones with powdered Oxone in the presence of potassium carbonate and tetrabutylammonium hydrogen sulfate has been developed.

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