4.8 Article

A Broadly Applicable Mild Method for the Synthesis of gem-Diperoxides from Corresponding Ketones or 1,3-Dioxolanes

Journal

ORGANIC LETTERS
Volume 11, Issue 7, Pages 1615-1618

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol900262t

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Funding

  1. National Natural Science Foundation of China [20672129, 20621062, 20772143]
  2. Chinese Academy of Sciences [KJCX2.YW.H08]

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Ketones or ketals were readily converted into the corresponding gem-dihydroperoxides in high yields by treatment with ethereal H2O2 at ambient temperature in the presence of 2-5 mol % of phosphomolybdic acid.

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