4.8 Article

A New Route to Substituted Phenols by Cationic Rhodium(I)/BINAP Complex-Catalyzed Decarboxylative [2+2+2] Cycloaddition

Journal

ORGANIC LETTERS
Volume 11, Issue 6, Pages 1337-1340

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol900123d

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A new route to substituted phenols has been developed by cationic rhodium(I)/BINAP complex-catalyzed decarboxylative [2 + 2 + 2] cycloadditions of 1,6- and 1,7-diynes with commercially available vinylene carbonate.

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