Journal
ORGANIC LETTERS
Volume 11, Issue 19, Pages 4306-4309Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901610a
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [18064006, 2075003]
- Global COE
- Tosoh Finechem
- Tosoh Corps.
- Chisso Corp.
- Grants-in-Aid for Scientific Research [18064006] Funding Source: KAKEN
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Iron-catalyzed cross-coupling reactions of primary and secondary alkyl sulfonates with arylzinc reagents proceed smoothly in the presence of excess TMEDA and a concomitant magnesium salt. The arylzinc reagents are prepared from the corresponding aryllithium or magnesium reagents with ZnI2. The in situ formation of alkyl Iodides and consecutive rapid cross-coupling avoids discrete preparation of the unstable secondary alkyl halides and also achieves high product selectivity.
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