4.8 Article

A Guanidinium Ion-Based Anion- and Solvent Polarity-Controllable Molecular Switch

Journal

ORGANIC LETTERS
Volume 11, Issue 3, Pages 613-616

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol802638k

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Funding

  1. National Science Council (Taiwan) [NSC-95-2113-M-002-016-MY3]

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The macrocycle bis-p-xylyl[26]crown-6 (BPX26C6) is capable of complexing guanidinium ions in a [2]pseudorotaxane-like manner in solution. A corresponding molecular switch can be operated through changes in solvent polarity or the addition and removal of halogen and acetate anions.

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