4.8 Article

Synthesis of a BDPA-TEMPO Biradical

Journal

ORGANIC LETTERS
Volume 11, Issue 9, Pages 1871-1874

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol9001575

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Funding

  1. National Science Foundation [DMR-0706408]
  2. National Institute of Biomedical Imaging and Bioengineering [EB-002804, EB-002026]

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The synthesis and characterization of a biradical containing a 1,3-bisdiphenylene-2-phenylailyI (BDPA) free radical covalently attached to a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) free radical are described. The synthesis of the biradical is a step toward improved polarizing agents for dynamic nuclear polarization (DNP).

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