Journal
ORGANIC LETTERS
Volume 11, Issue 1, Pages 205-208Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802379b
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Funding
- DGESIC [CTQ2005-03124]
- Consolider Ingenio [CSD2006-0003]
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A general and efficient protocol for the enantloselective synthesis of sphingosine, phythosphingosine, and 4-substituted derivatives was established. These compounds were obtained from a common intermediate prepared from butadiene monoepoxide by a synthetic sequence Involving enantioselective allylic substitution, cross-metathesis, and dihydroxylation.
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