Journal
ORGANIC LETTERS
Volume 11, Issue 16, Pages 3630-3632Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901367m
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Funding
- Sumitomo Foundation
- Sankyo Foundation of Life Science to MI
- JSPS
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Direct hydroxylation of tertiary C-H bonds for construction of 1,3-diaxial diol derivatives was achieved by devising a new detachable dioxirane precursor containing a trifluoromethyl ketone moiety and ethylene tether. Oxone treatment of the ketones led to the corresponding dioxiranes, enabling hydroxy group installment into cyclohexane and steroid derivatives in a regio- and stereoselective manner through intramolecular oxygen insertion.
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