Journal
ORGANIC LETTERS
Volume 11, Issue 8, Pages 1841-1844Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900344g
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Funding
- National Natural Science Foundation of China [2080-2047]
- Bureau of Education, Jiangsu Province [08KJD150005]
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An intriguing new Wacker-type oxidation of alkynes catalyzed by PdBr2 and CuBr2 is described, which opens an efficient access to 1,2-diketones using molecular oxygen. Under the optimized conditions, a variety of alkynes, including diarylalkynes, arylalkylalkynes, and dialkylalkynes, were compatible substrates in this transformation. The mechanism of this reaction was preliminarily investigated by control experiments.
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