4.8 Article

Regioselective Ruthenium-Catalyzed Direct Benzylations of Arenes through C-H Bond Cleavages

Journal

ORGANIC LETTERS
Volume 11, Issue 21, Pages 4966-4969

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol902115f

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Funding

  1. DFG

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Highly regioselective ruthenium-catalyzed direct benzylations through C-H bond cleavages were accomplished under remarkably mild, nonacidic reaction conditions, for which experimental studies suggested a SEAr-type mechanism not to be operative.

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